A S‐Scheme MOF‐on‐MOF Heterostructure

نویسندگان

چکیده

Constructing MOF-on-MOF heterojunction with elaborate charge transfer mechanism and interface is a promising strategy for improving the photocatalytic properties of MOFs. Herein, Step-scheme (S-scheme) MIL-125-NH2@CoFe Prussian blue analogue (PBA) reported first time. The heterostructure exhibits sandwich-like morphology hollow CoFe PBA nanocages selectively assembled on top-down surfaces MIL-125-NH2 nanocakes. Experimental findings theoretical simulation results reveal formation internal electric field via interfacial TiOCo bonds at heterojunction, providing driving force atomic transportation highway accelerating S-scheme enhancing redox performance. Contributed further by structures increased active site exposure, designed significantly enhanced activity degradation various organic pollutants. This study provides insights toward rational design semiconducting MOF-based heterojunctions improved properties.

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ژورنال

عنوان ژورنال: Advanced Functional Materials

سال: 2023

ISSN: ['1616-301X', '1616-3028']

DOI: https://doi.org/10.1002/adfm.202214627